No MCE2005 doesn't look like XP Pro. XP Home is out of the question you must get Pro or MCE2005.
This is the these instead of grey it's tan and has a more elegant theme than XP Pro's Fisher Price toy blue.
Start Menu looks better than this but I have it "stacked up 3 layers so I can view my quickluanch toolbar. So it looks better if it's not "stacked" or stretched.