yes but a few things also needs to be done.
You need to change the default listening port for rdc on the other machine.
How to change the listening port for Remote Desktop
default is 3389 so change it on that machine to something like 3379
Then you set up a port forward of 3379 to the ip of that computer.
then for fun lets say your external ip is 55.217.33.45.
from outside the network you would just type the ip to access the machine on the default port.
To get the other one you would enter 55.217.33.45:3379