which graphics card is better ? Out of these two

If you're building just a little web cruiser then either will do. Don't expect any thing marvelous really out of either one.
Unless you are getting one or the other for free, spend the few bucks on something a bit more recent... an Nvidia 610 or 620 is a whole lot better than those, can typically be found for under $50.

Unless there is a specific reason you selected two with s-video output?
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