There is all the info you need about RAID. Basically RAID takes the information and splits it among the 2 drives. So having Windows on a single drive it will not have that information on the 2nd drive when you go to implement the RAID. Which will only make your life more difficult.
Seeing as you are gonig for RAID1 i dont think you can. As how can it mirror something that is already installed? Meaning how can it mirror the OS if you already installed the OS? It wont jsut take the OS and mirror it after you setup RAID.
Cheers,
Mak