What kind of software are you using?
The same thing happens to me when I put in a blank disc. Roxio has a program called Drag-to-Disk. It enables you to write to the disc like you would any other drive. This is usually a feature that comes with most cd burning software. If you do not have cd burning software, it will tell you that the D:\ drive is not accessible.
If you don't have software...
Or google it....
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