Always go with the BIOS for vcore readings. Try EVEREST Home Edition for more OC'ing/temperture information. (EVEREST isn't supported by the makers, just google "EVEREST Home edition download" and you'll get some links).
You have a FSB/RAM ratio on if your ram is running slower than your CPU. If your sure that your CPU maxes out at 225, then try making the divider smaller to boost your RAM speed. (if you have good RAM, you might be able to OC it a little bit, depends on the model/maker though).
Woah, you might want to lower then voltage to your ram. Mine is running at 210MHz and only using 2.675 volts. If you do lower it, run Memtest to check for errors, then Prime95.
Summary:
If you really have a fsb:ram divider on, and your CPU can only handle 225 with plenty of volts, then your CPU is at it's max.
If you have NO fsb:ram divider on, your ram is running at the same MHz as the CPU, and you can't OC anymore...it's most likely the RAM holding you back.
EDIT: Ah, you don't have dividers on your BIOS? Then keep the RAM at standard 200, and OC only the CPU...and find the max. Reverse the operation and find your RAM's max. Compare results and try to use a combonation of both to have a stable and decent OC.