Need to see the users in the Administrators Group.
Simply put, the easiest way to do this, is by doing the following.
Create 2 accounts (which you have done). Leave the account you want to use as is, and change the other account to the admins group. Logon as the account you want to use, once. This will create the folders and registry hive for it. Then log off and on as the other account you created. Delete the Documents and settings directory of the account you just created, and copy the administrators Folder on the same directory. It will be named "Copy of ..." Rename is to the same name that you had as the account you wanted to use. This will link the registry environment to the profile. That is all the copy to does.
Then delete the profile you are logged on as, from under the admins account, and log on as the new user. This should word for you.
Good luck