Overclocking if you want to take the risk (I don't suggest OCing your CPU unless you have aftermarket cooling and a full understanding of how to do it),
Turning off ALL background processes when you jump into a game (AV, messenger programs, browsers, everything),
or save up more money to get a better upgrade.
Ultimately, the more powerful the GPU the more FPS you will gain. That said, a more powerful CPU will give slight gains in performance depending on what game it is and how powerful the GPU is.